In the early days of insulating attics, people believed the insulation was a heat source. That’s not the case, as the insulation is actually a barrier between two areas of different temperatures. As for the “hot roof” theory, the unvented attic system could make the temperature of the roof go up a little, but this increase won’t cause damage to your shingles.
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The Canadian National Building Code references the CAN/ULC S705.2 National Application Standard which must be followed during all installations of 2lb medium density closed cell polyurethane foam. Every installer of CAN/ULC-S705.1 compliant medium density, spray applied foam must be licensed in order to spray foam and hold valid photo ID issued by their Quality Assurance Program (QAP) provider showing their license is in good standing.
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Part of that guidance will be explaining that interior, two component foam is applied with the professional using specific personal protective equipment (high-pressure foam is installed while using a respirator, for example). It is encouraged that professionals explain clearly to customers that this equipment, coupled with certain work and engineering practices, including ventilation, is used to minimize exposures to the chemicals used to make SPF during the job.
If what you are looking for is a fiberglass roof coating for your recreational vehicle, then the Dicor RPFRC1, which is available in a 1-gallon container is an ideal option. It makes use of a hundred percent acrylic fiberglass resins formula, which is effective in providing a more flexible coating, which tends to contract and expand with each roof movement.