If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.

I don't know if it's common or uncommon, but installing a layer of rigid foam above your roof sheathing in order to interrupt thermal bridging is always a good idea, and is preferable in all respects to a roof assembly without any rigid foam above the sheathing. If you decide to install rigid foam above the roof sheathing, you shouldn't use closed-cell spray foam under the sheathing; either use open-cell spray foam (which is vapor-permeable) or a fluffy insulation like cellulose, mineral wool, or fiberglass (any of which will allow the roof sheathing to dry to the interior).

How Much Is Open Cell Spray Foam Insulation

Note: The practice of foam insulating the attic has raised eyebrows in the building industry because "standard" roofing techniques call for the attic to be ventilated; however, in a vented attic situation it will become approximately 130 degrees in the summer. There's no reason for an air-conditioning and vent-ductwork to have to work in that type of severe conditions. By applying Icynene right on the underside of the roof deck, the severe temperatures no longer exist in the attic. In short, the attic is now a "conditioned" space of the house that is just as comfortable as any other room in the home. This is called a "Compact Roof", which means you can frame right up against it. The one drawback of using expanded foam on the inside of the roof is that this will cause the temperature of the shingles to rise, but how much is not yet known. And how much damage a rise in temperatures could cause is debatable.
RE: my June 12 post...We went ahead and had the attic sprayed with a Soy-based product. Stayed in a hotel for 3 nites. Still smelled a little bad but that's gone away over time. I'm very glad we didn't use the other foam as even that much outgassing of a petrochemical could have sent my wife to the hospital. Unfortunately, the spray crew didn't speak English(at least not to me) and were kinda lazy, so they ended up spraying over some can fixtures from the kitchen below that were not insulation-contact rated. So I hired an electrician to come out, pull down the cans, pull out what he thought was an appropriate amount of foam to create a big enough air space and then re-install the cans. I billed the firm for the electrician plus an extra night we had to stay in the hotel and they paid, no questions asked. Guess they knew they had screwed up.  
Carefully examine the roof membrane (surface material) for cracks, tears, blisters, evidence of ponding, exposed foam, and open seams. If already coated, evaluate the condition of the coating. Pay particular attention to areas around roof penetrations (vents, skylights, pipes, etc), ponding areas, cracks in parapet walls, and the attachment of roof membranes to parapet walls. Roofs should be in good condition to warrant coating. http://y2u.be/ggLAUsiuI_o
It is also capable of reflecting more than 90% of the sun’s rays, which further increases its protective nature. In addition, it offers protection from moisture while also being designed to be sturdy regardless of the weather and climate it is exposed in. Such is the main reason why many view it as capable of forming a thick blanket of protection, which is similar to rubber. https://m.youtube.com/embed/ggLAUsiuI_o
Note:  A board foot is defined as a 12" x 12" square at 1" thick. Actual output can be affected by a number of factors including temperature and humidity. The theoretical yield has become an industry standard for identifying certain sizes of two component kits. Theoretical yield calculations are performed in perfect laboratory conditions, without taking into account the loss of blowing agent or the variations in application methods and types.
We live in middle TN and had our house foamed last year. We noticed recently that some of the foam was shrinking and seperating from the floor joists. We contacted the installer and he informed us that the manufacturer had a problem with a batch of foam during the time frame we had our house sprayed. The contractor wasn't sure if we had the recalled batch installed in our house or not. He said he would check the batch numbers and let us know. He seems like a nice guy promising to do whatever it takes to fix any problems. Do we trust him, however, to be truthful about the batch number? Do we have any options for finding out the information ourselves? I inspected the entire crawl space of the house and noticed approximately (5) areas that were seperating and a couple areas where the foam didn't adhere to the block. Do I assume by it being so infrequent that it is nothing to be concerned about? My concern is the walls that are not capable of being visually inspected because of sheetrock.
Thank you, Allison. We have a split system unit (actually 5) with the heat being propane. The foam guy said that it needed ventilation, so completely sealing the attic wouldn't be a good idea. It sounds like you are saying that the systems need to be vented out of the attic or replaced with some type of closed system. But I shouldn't bother spraying if the plan is to leave the soffet vents open. Is that correct?

How Much For Spray Foam Roof

This stuff works GREAT ! I live in an older mobile home that had a lot of leaks when I moved-in. I worked for two years to locate and fix them all. Now I simply go over all of the repaired places once a year just to be sure everything is OK. NO LEAKS FOR 4 YEARS NOW!!  Others here use "sno proof" or something that does not stop leaks. When I tell them about my success, they don't seem to want to pay the$ for this superior product. Too bad!. I used the tape in  repairing the leaks.

Spray Foam Roof Insulation