Spray polyurethane foam, or SPF, is the main type of 2-part, closed-cell spray foam used by insulation contractors. Large-scale insulation jobs require special equipment as well as safety gear to protect the installer from chemical fumes during installation. When the foam cures and hardens just several minutes after application, it's completely safe for as long as it stays in place.
Check with the coating manufacturer who may be able to suggest applicators who have used their products and have familiarity with the application. Another option would be to interview contractors and ask specific questions about their proven ability to install roof coatings. Contractors affiliated with the National Roofing Contractors Association (NRCA) or local roofing contractor trade associations typically are more knowledgeable. Consult those groups’ websites for contractors.
One thing I wanted to mention was that I think your price point is a little high and that might deter people from considering spray foam. As a project manager for a spray foam company for years I can tell you that we offer 0.5 Lb. open-cell foam at around $.25/board foot. We even offer a 1.0 Lb. open-cell foam for less/the same cost as you quoted the 0.5 Lb. foam for above. The 1/0 Lb. open-cell foam has an R-value of almost 5.
Roof Coatings should not be confused with deck coatings. Deck coatings are traffic bearing - designed for waterproofing areas where pedestrian (and in some cases vehicular) traffic is expected. Roof coatings will only waterproof the substrates but will not withstand any kind of on going use by people or vehicles (such as walkways, patios, sundecks, restaurants, etc.).
You can also take advantage of Heng’s rubber roof coating if you need to coat your RV’s rubber roof. It works well in sealing EPDM rubber roofs. It is also useful on seams and tears as well as in sealing vents and air conditioning units. This roof coating is a good choice if you are just in search of that with a 1-gallon capacity at the most reasonable price.